Spin-Crossover Materials

Spin-Crossover Materials

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The phenomenon of spin-crossover has a large impact on the physical properties of a solid material, including its colour, magnetic moment, and electrical resistance. Some materials also show a structural phase change during the transition. Several practical applications of spin-crossover materials have been demonstrated including display and memory devices, electrical and electroluminescent devices, and MRI contrast agents. Switchable liquid crystals, nanoparticles, and thin films of spin-crossover materials have also been achieved. Spin-Crossover Materials: Properties and Applications presents a comprehensivesurvey of recent developments in spin-crossover research, highlighting the multidisciplinary nature of this rapidly expanding field. Following an introductory chapter which describes the spin-crossover phenomenon and historical development of the field, the book goes on to cover a wide range of topics including Spin-crossover in mononuclear, polynuclear and polymeric complexes Structure: function relationships in molecular spin-crossover materials Charge-transfer-induced spin-transitions Reversible spin-pairing in crystalline organic radicals Spin-state switching in solution Spin-crossover compounds in multifunctional switchable materials and nanotechnology Physical and theoretical methods for studying spin-crossover materials Spin-Crossover Materials: Properties and Applications is a valuable resource for academic researchers working in the field of spin-crossover materials and topics related to crystal engineering, solid state chemistry and physics, and molecular materials. Postgraduate students will also find this book useful as a comprehensive introduction to the field.Properties and Applications Malcolm A. Halcrow. structure of molecules. J. Am. Chem. Soc., 53: 1367-1400. 4. ... Advanced Electronic Structure Theory. ... Chem. Acc., 107: 48-55. 13. Fouqueau, A., Casida, M. E., Daku, L. M. L., Hauser, A., Neese, F. (2005) Comparison of density ... A. (2007) DFT calculations on the spin -crossover complex Fe(salen)(NO): a quest for the best functional. J. Phys. Chem.

Title:Spin-Crossover Materials
Author:Malcolm A. Halcrow
Publisher:John Wiley & Sons - 2013-01-07


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