This volume provides an in-depth overview of the chemistry of metalloporphyrins as oxidation catalysts in chemical and biological systems. It discusses practical techniques for the synthesis of metalloporphyrins and introduces useful methods of immobilization to improve their synthetic utility. Detailed discussions of underlying mechanistic features are provided.The demands on the basis set increase with the quest for detail in the electronic structure. ... The extended Hiickel approach [9a] is a simple quantum chemical cai- culational procedure which, when applied to ... Two slightly different semiempirieal approaches have been applied to study oxometallo- porphyrins and their reactions; the MINDO  and AMI  and the INDO  calculations.
|Title||:||Metalloporphyrins in Catalytic Oxidations|
|Author||:||Roger A. Sheldon|
|Publisher||:||CRC Press - 1994-06-28|